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Discharge principle: The charge and discharge reaction of lithium iron phosphate batteries takes place between LiFePO4 and FePO4 phases. During the charging process, LiFePO4 gradually separates from lithium ions to form FePO4. During the discharge process, lithium ions are embedded in FePO4 to form LiFePO4.
Why lithium iron phosphate batteries are not easy to use in winter? I summarize the following two points for your reference.
1. Firstly, there are some performance defects in lithium iron phosphate batteries. The principle of lithium iron phosphate batteries is also discussed above. In low-temperature environments, the electrolyte moves quite slowly, which affects the transfer activity of lithium ions between positive and negative electrodes, leading to a decrease in battery charging and discharging performance. Simply put, in a low-temperature environment, it is not that the lithium battery is truly dead, but rather that it is charged but cannot be released normally.
2. Secondly, its low-temperature performance is relatively poor, and many tests have shown that lithium iron phosphate batteries cannot drive electric vehicles at low temperatures (below 0 ℃). Although some manufacturers claim that the capacity retention rate of lithium iron phosphate batteries is good at low temperatures, that is when the discharge current is small and the discharge cutoff voltage is very low. According to analysis data, ordinary lithium batteries can reduce their capacity by 20% at zero degrees Celsius, but when they reach minus 10 degrees Celsius, their capacity may only be about half.
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